Synthesis, polymerization, and unusual properties of new star-shaped thiophene oligomers.
نویسندگان
چکیده
Terthienobenzene (TTB, 6) was prepared through a new, high yield route along with pi-extended derivatives 10 and 11. Electropolymerization of tris-EDOT derivative 11 results in a highly stable cross-linked conjugated polymer that shows polaron confinement between the TTB units as confirmed by UV-vis-NIR spectroelectrochemistry and EPR.
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ورودعنوان ژورنال:
- Organic letters
دوره 11 15 شماره
صفحات -
تاریخ انتشار 2009